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11.
用XRD、IR和TPR等技术研究了钙钛矿型复合氧化物的晶体结构及其反应性能.整个组成范围内,LaNi_(i-x)Mn_xO_3(0.0≤x≤1.0)体系都生成单一钙钛矿相;x=0.0,0.6≤X≤1.0时为菱形晶系,0.2≤x≤0.5为立方晶系.IR和TPR研究表明,晶体结构对B—O键合作用存在较大影响.CO微反考察表明,本体系的催化活性与晶系存在密切关系,晶体对称性越高,反应活性越低.说明钙钛矿型复合氧化物的催化活性与体系活性中心的B—O键合作用能力有关. 相似文献
12.
Manfred Sommer 《Constructive Approximation》2006,23(2):211-227
Hermite interpolation of 2n + k data by spline spaces of order k with n variable knots counting multiplicities is studied.
A characterization of the minimal spline spaces which admit a solution of the interpolation problem is obtained. A sufficient
condition on uniqueness of interpolating spline functions is given. 相似文献
13.
We study problems of interpolation of positive linear operators in couples of ordered Banach spaces. From this viewpoint, we study couples of noncommutative spaces L 1, L ∞ associated with weights and traces on von Neumann algebras. 相似文献
14.
The knowledge of hydrocarbon/water phase equilibria is important in the design and operation of equipment for petroleum transport and refining and petrochemical plants. The presence of water in a hydrocarbon mixture can affect the product quality and damage the operation equipment due to corrosion and formation of gas hydrates. Tracing the concentration of hydrocarbons in aqueous media is also important for technical purposes like preventing oil spills and for ecological concerns such as predicting the fate of these organic pollutants in the environment. 相似文献
15.
Wilson A. Cañas-Marín Julián D. Ortiz-Arango Uriel E. Guerrero-Aconcha Claudia P. Soto-Tavera 《Fluid Phase Equilibria》2007
The ability of Soave–Redlich–Kwong cubic equation of state (SRK EoS) to predict densities and thermodynamic derivative properties such as thermal expansivity, isothermal compressibility, calorific capacity, and Joule–Thompson coefficients, for two gas condensates over a wide range of pressures (up to 110 MPa) was studied. The predictions of the EoS were compared to Monte Carlo simulation data obtained by Lagache et al. [M.H. Lagache, P. Ungerer, A. Boutin, Fluid Phase Equilibr. 220 (2004) 221]. Two completely different alpha functions for the SRK EoS attractive term were used and their respective effects on the predictions of such properties were analyzed. Also, two different forms of the crossed terms of the attractive parameter, aij, and three expressions of the crossed terms of the repulsive parameter, bij, were combined in different ways, and predictions were carried out. Little sensitivity of the properties on the chosen alpha function, except for the calorific capacities, was found in the systems studied. The most commonly used combination rules to model phase behavior of reservoir fluids, i.e. geometric and arithmetic forms of aij and bij, respectively, predicted very deficient results for these fluids at extreme conditions, specially for density calculations. 相似文献
16.
本文针对一类非饱和土壤水流问题,提出了基于二次插值的特征差分格式,得到了严谨的L2模误差估计.并作了数值试验,指明方法的有效性. 相似文献
17.
Spectral and Pseudospectral Approximations Using Hermite Functions: Application to the Dirac Equation 总被引:1,自引:0,他引:1
We consider in this paper spectral and pseudospectral approximations using Hermite functions for PDEs on the whole line. We first develop some basic approximation results associated with the projections and interpolations in the spaces spanned by Hermite functions. These results play important roles in the analysis of the related spectral and pseudospectral methods. We then consider, as an example of applications, spectral and pseudospectral approximations of the Dirac equation using Hermite functions. In particular, these schemes preserve the essential conservation property of the Dirac equation. We also present some numerical results which illustrate the effectiveness of these methods. 相似文献
18.
本文将在切触有理插值中起重要作用的Salzer定理推广到了多元向量的情形. 相似文献
19.
Let E\subset \Bbb R
s
be compact and let d
n
E
denote the dimension of the space of polynomials of degree at most n in s variables restricted to E . We introduce the notion of an asymptotic interpolation measure (AIM). Such a measure, if it exists , describes the asymptotic behavior of any scheme τ
n
={ \bf x
k,n
}
k=1
dnE
, n=1,2,\ldots , of nodes for multivariate polynomial interpolation for which the norms of the corresponding interpolation operators do
not grow geometrically large with n . We demonstrate the existence of AIMs for the finite union of compact subsets of certain algebraic curves in R
2
. It turns out that the theory of logarithmic potentials with external fields plays a useful role in the investigation. Furthermore,
for the sets mentioned above, we give a computationally simple construction for ``good' interpolation schemes.
November 9, 2000. Date revised: August 4, 2001. Date accepted: September 14, 2001. 相似文献
20.
Bernard Bialecki 《Numerical Algorithms》1994,8(2):167-184
Cyclic reduction and Fourier analysis-cyclic reduction (FACR) methods are presented for the solution of the linear systems which arise when orthogonal spline collocation with piecewise Hermite bicubics is applied to boundary value problems for certain separable partial differential equations on a rectangle. On anN×N uniform partition, the cyclic reduction and Fourier analysis-cyclic reduction methods requireO(N
2log2
N) andO(N
2log2log2
N) arithmetic operations, respectively. 相似文献